A hexaicosametallic copper(II) phosphonate.

نویسندگان

  • Vadapalli Chandrasekhar
  • Dipankar Sahoo
  • Ramakirushnan Suriya Narayanan
  • Raymond J Butcher
  • Franscesc Lloret
  • Emilio Pardo
چکیده

Structure and characterization of [Cu26{2,3,5,6-(Me)4C6H-CH2-PO3}18(μ2-OH)4(μ3-OH)6(μ4-Cl)6(μ-OH2)2(OH2)2(MeCN)4]·6MeCN·15H2O (1) is reported. Complex 1 is the largest discrete molecular homometallic transition metal phosphonate assembly. Remarkably, this gigantic molecular phosphonate has been prepared at room temperature using a normal solution synthetic method.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 23  شماره 

صفحات  -

تاریخ انتشار 2013